When I started out I used FrontPage in design mode. I then moved to designing the layout in FrontPage and then designing the rest of the site and a little bit of coding in Dreamweaver.
Three years on I now use Dreamweaver to code up HTML/CSS, and then NetBeans IDE for true development.
To answer your question, I find that Dremweaver is the best tool for website creation, as it gives you great design preview options, coupled with code-completion for HTML/CSS.
One thing to watch out for is cross-browser issues. As a beginner, I had no idea that a website could look different in different browsers.
This meant that a lot of my initial websites rendered fine when viewed in Firefox and Chrome, but very poorly when in IE.