Hi, I actually have a Masters in VFX for film and television, from a top tier University. My masters was specialised in Nuke, I'm a top rung nuke operator, I use After Effects for a lot of jobs, mainly for time. I work in nuke for photo-realistic cinema work you can spend months perfecting and After Effects for fast easy jobs like web promos. The only time I use nuke for a web job is when I have a bit of time and I want to brush up my nuke skills.
I have various qualifications in both if someone needs a hand with something PM me and I'll try and help you out.