The most common of which is to invite them to groups and fan pages.
People pay $3 for 5000 friends invited.
If you made a facebook page and invited 15,000 to it its a good basis,
when the page is larger you can send out cpa offers etc...
So not only making money from a group but making money inviting to other groups.
You can also sell accounts with 1500 friends for $10-12 i do believe,
so its up to you what you did with them,
those are a few ideas for now.