No, to both of you.
The logical progression should be to learn javascript then learn jQuery to make many of the difficult javascript tasks easier.
That would be like implementing a data structure you know nothing about into a software program without understanding how the data is actually stored in memory. Or using a PHP framework before actually learning PHP.
Or for people who don't do much programming, it's the same concept that applies when your math teacher teaches you the hard way to solve a problem before teaching you the formula or other easy way. Otherwise, you know the formula gives you the right answer, and it's easy to use, but you don't know why it gives you the right answer, and ultimately you're no smarter than you were before.
It makes no sense to suggest that he start using a framework before learning about the underlying foundation, else he won't truly know what he's doing. It's irresponsible to suggest something like that to someone just because it's "easier," and ultimately you're doing him more harm than good.
You don't build the walls of a house and then put the foundation down after the house is built. That's just rampantly moronic.