A copyright complaint directly to Facebook or to him himself could be a problem, but we can not see the future so no one can tell you the answer with certainty. Maybe the supplier gave him permission to use it, if not, no one can tell you one way or another if they will go after him for copyright or not. Not everyone is aware if their content is stolen and some people even if they are made aware of it don't care.
Your best bet is to go to the content owner and ask them directly if you're worried about copyright related repercussions.