Both are fine. Most Chinese have both so you can have either one if you can't get both. WeChat is more than a payment tool. You can also use it to promote your products which is a huge advantage over alipay.
Wechat is the defacto in china. Everyone has it. So may be best to aim for that one and when you have developed your system, and it is making money, then you can move onto alipay
If you do want to sell something to the Chinese, You should at least have one of them. For me, Alipay is better for business given it's the authorized payment gateway of Alibaba Corporation.
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