I am no expert, but I will try to make sense (whatever little I can).
The error thrown is by urllib, not by selenium.
I think the localhost service (which is your selenium server?) at port 4444 is not responding as it should, resulting in this error.
I have never encountered a urllib error when using chrome with the latest chromedriver, so I am pretty sure it has to do with remote driver (which might be using the urllib to connect to the remote selenium service?)
Maybe you should switch to webdriver.Chrome(executable_path="file/path/to/latestchromedriver")
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