Members that have already joined your page will not be "selectable" anymore, meaning the little box you tick to invite them will go gray.
As for members that have already been invited yet have rejected the invitation, there's no easy way of keeping track of them.
Just send bulk invites to all of your friends again, there's no real harm in that.
Unless you're getting 1k new friend requests on a nightly basis (I'd just wait to hit the limit of 5k before sending invites), getting 50-100 new friends isn't going to be the difference between making a page go viral or having it die out.