It could work - a lot of depending factors.
It pays $25 a sign up but does anyone sign up? What's the landing page like? Is there a demand for specifically the education you speak of.
Yeah give it a try - that way you will learn first hand knowledge - but I would at least get your own domain and cloak the affiliate link.
Do Facebook even allow direct links to affiliate offers in there ad program? A lot of providers don't - look at FBs official terms to check what they say is allowed on their network.
Reminds me of something the user who introcuded me to this forum years back taught me: he was running iframe scripts over AdultFriendFinder landing pages to turn them into "MillionaireFriendFinder" landing pages, cloaked domain... I'm sure he was stuffing but I'm literally not even sure if you're allowed to talk about that here.