Why would an Internet marketing company hire someone with absolutely no experience? What an enigma!
Do you mean that you are a newly self-employed affiliate who is using an affiliate program? If so, which affiliate program are you using? I can probably help you find a method if I had more information about this. For now, I'm going to suggest using Craigslist to advertise the webcam and dating site links (no, do
not use it to post the links, I will explain more momentarily).
Method 1
Just go on there pretending to be one of the cam girls, chat with the lonely singles, tell them about your "chat room" and how you normally don't tell anyone because you're embarrassed, and then send them the cloaked affiliate link.
Method 2
Go on Craigslist again and chat with the lonely singles. Tell them you would feel more comfortable talking to them through the dating website because they verify that you are a real person (or use some other excuse). They'll sign up to talk to you and you'll get paid.
By the way, I would question the veracity of a 2 1/2 year old method created by someone named "damn1337" who currently has 61 posts.