Actually you can but it seems to be available to businesses only - go to www.facebook.com/business and submit a request (you’ll need to prove you're the owner of both accounts).
I think you get paid to your bank account by Shopify. You get your payments in 3 days and most products are shipped in 2-3 weeks. Just wait until you get paid to order the product. 3 days doesn't make a big difference.
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