You can make it a website in photoshop, use the slicing tool to section out pieces. Then you can make certain slices link to certain areas.
For example a facebook logo could link to FB.
Then you save for 'web & devices' and in the drop down menu just pick HTML & images. Edit what you need, and press save. Job done.
I was going to say this also, but can you make links to different pages using PS or is it simply going to make the template?
Either way Dreamweaver is pretty much the cream of the crop. Best I have used anyway.