How To Make A WordPress Homepage Like Labnol.org?

If you look at labnol.org, you will find that it has some special features where in Around the Web section is present towards the right along with the list of articles. Below that a feature article section is present and again the chronological list of article follows. Then follows the post from 2 categories.

Also the archive pages are too good. So please give me any hint on how to do this?

It would involve making a custom page template for your theme. Get to reading on 'the loop'.