I started with adwords, did well and am still doing well,

So I decided to take a crack at facebook ads and Biing/yahoo

Well both campaigns have been up for 2 days and not 1 impression ads are approved, and I have made the suggested amount way above and I am still not getting anything.

any tips or guides or anything will be greatly appreciated

Did you check your settings on your ad creative? Which countries do you have selected to run ads on? Did you target any interests and links?